| 配合物[Co(benimtacn)Cl2]Cl·3H2O的合成、晶体结构及电化学性质 |
| Synthesis, Crystal Structure and Electrochemical Properties of Complex [Co(benimtacn)Cl2]Cl·3H2O |
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| 摘要: |
| 关键词: 亚甲基苯并咪唑 1，4，7三氮环壬烷 钴配合物 晶体结构 电化学性质 |
| 基金项目: |
| Abstract: Synthesis, crystal structure and the electrochemical properties of the complex [Co(benimtacn)Cl2]Cl·3H2O (benimtacn= 1-(Benzimidazol-2-ylmethyl)-1,4,7-triazacyclononane) are reported. The result shows that the complex crystallizes in the orthorhombic system, space group Pbca with lattice parameters a=1.131 13(15) nm, b=1.345 00(18) nm, c=2.567 6(4) nm, and Dc=1.621 g·cm-3, Z=8. The coordination number of cobalt(III) is six; it is located in the center of a slightly distorted octahedron. A chloride ion and three water moleculars are out of the complex ion. CCDC: 634987. |
| Keywords: benzimidazol-2-ylmethyl 1,4,7-triazacyclononane complex of cobalt(III) crystal structure electrochemical properties |
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| 李庆祥,喻玖宏,肖海燕,杨祥良,徐辉碧.配合物[Co(benimtacn)Cl2]Cl·3H2O的合成、晶体结构及电化学性质[J].无机化学学报,2007,23(4):673-676. |
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