配合物[Cu(o-ABA)2(2,2′-bipy)]·(H2O)的水热合成、晶体结构及电化学性质
Hydrothermal Synthesis, Crystal Structure and Electrochemical Properties of the Complex [Cu(o-ABA)2(2,2′-bipy)]·(H2O)
作者单位
李薇 衡阳师范学院化学与材料科学系衡阳 421008 
李昶红 湖南工学院化工系衡阳 421008 
杨颖群 衡阳师范学院化学与材料科学系衡阳 421008 
匡云飞 衡阳师范学院化学与材料科学系衡阳 421008 
摘要: 
关键词: 铜(II)配合物  水热合成  电化学性质
基金项目: 
Abstract: The title complex has been synthesized by o-acetamidobenzoic acid and 2,2′-bipyridine(bipy) in the mixture solvent of water and methanol. It crystallizes(C28H26CuN4O7, Mr=594.07) in Triclinic space group P1 with a=0.805 3(4) nm, b=0.845 5(4) nm, c=2.001 8(9) nm; α=100.797(8)°, β=93.054(7)°, γ=97.297(7)°, V=1.323 9(10) nm3, Dc=1.490 g·cm-3, Z=2, F(000)=614. R1=0.035 9, wR2=0.080 5. The crystal structure shows that the copper atom is coordinated with four oxygen atoms from two o-acetamidobenzoic acid and two nitrogen atoms from the 2,2′-bipyridine, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 619084.
Keywords: copper(II) complex  hydrothermal synthesis  electrochemical property
 
摘要点击次数:  1072
全文下载次数:  1235
李薇,李昶红,杨颖群,匡云飞.配合物[Cu(o-ABA)2(2,2′-bipy)]·(H2O)的水热合成、晶体结构及电化学性质[J].无机化学学报,2007,23(4):721-724.
查看全文  查看/发表评论  下载PDF阅读器
Support information: