配合物[Cu(NPA)2(Im)2(H2O)]·H2O的合成、晶体结构及电化学性质
Synthesis, Crystal Structure and Electrochemical Properties of [Cu(NPA)2(Im)2(H2O)]·H2O
作者单位
李东平 衡阳师范学院化学与材料科学系衡阳 421008 
陈志敏 衡阳师范学院化学与材料科学系衡阳 421008 
匡云飞 衡阳师范学院化学与材料科学系衡阳 421008 
邝代治 衡阳师范学院化学与材料科学系衡阳 421008 
摘要: 
关键词: 铜(II)配合物  N-苯基代邻氨基苯甲酸  晶体结构  π-π堆积  电化学性质
基金项目: 
Abstract: A novel copper(II) complex [Cu(NPA)2(Im)2(H2O)]·H2O has been synthesized (NPA=N-phenylanthranilic acid and Im=imidazole) and characterized by IR, elemental analysis and X-ray single crystal diffraction methods. It Crystallizes in Triclinic system, space group P1 with a=0.987 9(2) nm, b=1.075 7(3) nm, c=1.559 7(5) nm, α=104.18(10)°, β=108.14(10)°, γ=92.69(10)°, V=1.513 39(7) nm3, Z=2, Dc=1.447 g·cm-3, F(000)=684, R1=0.028 0, wR=0.083 1. The Cu(II) ion in the title complex is coordinated with two oxygen atoms from two N-phenylanthranilic acid in monodenate mode, two nitrogen atoms form two imidazole, and one oxygen atom from water, forming a distorted square-pyramid coordination geometry. CCDC: 638653.
Keywords: copper(II) complex  N-phenylanthranilic acid  crystal structure  π-π aromatic interactions  electrochemical properties
 
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李东平,陈志敏,匡云飞,邝代治.配合物[Cu(NPA)2(Im)2(H2O)]·H2O的合成、晶体结构及电化学性质[J].无机化学学报,2007,23(5):892-896.
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