配合物[Cu(CAM)(H2O)2]的水热合成与结构表征
Hydrothermal Synthesis and Crystal Structures of Complex [Cu(CAM)(H2O)2]
作者单位
高洪苓 天津大学化学系天津 300072 
崔建中 天津大学化学系天津 300072 
摘要: 
关键词: 4-羟基吡啶-2,6-二甲酸  铜配合物  晶体结构
基金项目: 
Abstract: A copper(II) complex [Cu(CAM)(H2O)2], (CAM=4-hydroxypyridine-2,6-dicarboxylic acid), has been hydr-othermally synthesized and characterized by elemental analysis, IR, and X-ray diffraction single crystal structure analysis. It belongs to triclinic system, with space group P1, a=0.783 3(3) nm, b=0.796 5(3) nm, c=0.798 6(3) nm, α=100.340(6)°, β=93.768(6)°, γ=109.348(5)°, V=0.458 3(3) nm3, Z=2. The copper(II) ion is 5-coordinated and exhi bits a distorted square pyramidal coordination environment. The two coordinated aqueous molecules and the oxygen atoms from the ligand generate the intermolecular hydrogen bonds, which result in the 2D supramolecular network. CCDC: 227156.
Keywords: 4-hydroxypyridine-2,6-dicarboxylic acid  copper(II) complex  crystal structure
 
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高洪苓,崔建中.配合物[Cu(CAM)(H2O)2]的水热合成与结构表征[J].无机化学学报,2007,23(6):1072-1074.
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