| 从配位聚合物到单分子化合物的转化：Demko-Sharpless四唑合成法制备两个新颖的Co(II)配合物(英文) |
| From Coordination Polymer to Monomeric Complex: Two Cobalt Complexes from a Single Demko-Sharpless′ s Tetrazole Synthesis Reaction |
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| 摘要: |
| 关键词: 配位聚合物 四唑 晶体结构 |
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| Abstract: The reaction of CoCl2·6H2O with 4-cyanopyridine N-oxide in the present of NaN3 affords two novel complexes, {[(POTZ)(H2O)2N3]Co(H2O)} (1) and Co(POTZ)2(H2O)4 (2) (POTZ=4-tetrazolyl pyridine N-oxide), which are two different phases yielded at different stages of a single Demko-Sharpless′ tetrazole synthesis reaction. Surprisingly the 1D chain coordination polymer 1 is almost completely converted into monomeric complex 2 in this reaction, and, in a separate test, 2 also can be converted into 1. CCDC: 641222, 1; 641223, 2. |
| Keywords: coordination polymer tetrazole crystal structure |
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| 瞿志荣.从配位聚合物到单分子化合物的转化：Demko-Sharpless四唑合成法制备两个新颖的Co(II)配合物(英文)[J].无机化学学报,2007,23(6):1117-1120. |
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