| Abstract: A manganese coordination polymer [Mn(3,5-Me2PhCO2)2(phen)]n(phen=1,10-phenanthroline) has been synthesized by hydrothermal methods. The crystal structure was determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group P1 with a=0.770 3(4) nm, b=1.145 2(6) nm, c=1.537 0(9) nm, α=78.182(9)°, β=77.170(9)°, γ=89.784(9)°, V=1.292 8(12) nm3, Z=2, Mr=533.47, Dc=1.370 g·cm-3, μ=0.549 mm-1, F(000)=554, Rint=0.043 4, R=0.060 8 ,wR=0.148 4. In the crystal the manganese atom is six-coordinated by two nitrogen atoms from phen and four oxygen atoms from four 3,5-dimethylbenzolate molecules, completing an octahedral geometry. And the title complex forms one-dimensional chain structure through bridging 3,5-dimethylbenzolate molecules. CCDC: 642920. |
| 张春华,李昶红,邝代治,陈满生,李薇,杨颖群,匡云飞.一维链状锰配位聚合物[Mn(3,5-Me2PhCO2)2(phen)]n的合成与晶体结构(英文)[J].无机化学学报,2007,23(7):1255-1258. |
