| 配合物[Ag(chlsp)2](F3CCOO)的合成，谱学和晶体结构（英文） |
| Synthesis， Spectra and Crystal Structure of Complex [Ag(chlsp)2](CF3CO2) |
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| 摘要: |
| 关键词: 反-4-(4-氯苯乙烯基)吡啶 银配合物 晶体结构 三维网络 |
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| Abstract: A silver(Ⅰ) complex [Ag(chlsp)2](CF3CO2)， (chlsp=(E)-4-(4-chlorostyryl) pyridine)， was synthesized by the reaction between AgCF3CO2 and chlsp in the anhydrous enthnol. The crystal structure of [Ag(chlsp)2](CF3CO2) was characterized by elemental analysis， IR and determined by using single crystal X-ray diffraction. The result shows that the complex crystallize in triclinic system， with space group P1， a=0.109 7(2) nm， b=0.111 7(2) nm， c=0.117 2(2) nm， α=73.60(3)°， β=85.03(3)°， γ=81.82(3)°， V=0.136 2(4) nm3， Z=2. The moleculars are connected by Ag…Ag and Ag…Cl interactions， resulting in a three-dimensional network. CCDC: 631131. |
| Keywords: (E)-4-(4-chlorostyryl) pyridine silver(Ⅰ) complex crystal structure three-dimensional network |
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| 高洪苓,林 通,亢惠娟,陈雄斌.配合物[Ag(chlsp)2](F3CCOO)的合成，谱学和晶体结构（英文）[J].无机化学学报,2007,23(8):1429-1431. |
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