| 配合物Cu(3，5-DMBA)2(phen)的合成、晶体结构及电化学性质 |
| Synthesis， Crystal Structure and Electrochemical Properties of Complex Cu(3，5-DMBA)2(phen) |
|
| 摘要: |
| 关键词: 铜(Ⅱ)配合物 晶体结构 电化学性质 |
| 基金项目: |
| Abstract: A copper(Ⅱ) complex Cu(3，5-DMBA)2(phen) has been synthesized by self-assembly of 3，5-dimethylbenzoic acid， 1，10-phenanthroline and copper perchlorate. Crystal data for this complex: Monoclinic， space group C2/c with a=2.348 3(5) nm， b=0.984 4(2) nm， c=1.138 4(2) nm， β=103.02(3)°， V=2.563 9(9) nm3， Dc=1.404 g·cm-3， Z=4， F(000)=1 124， final GooF=1.051， R1=0.035 0， wR2=0.099 8. The crystal structure shows that the copper atom is coordinated with two oxygen atoms from two 3，5-dimethylbenzoic acids and two nitrogen atoms from the 1，10-phenanthroline， forming a square-planar structure. The result of the cyclic voltametric behavior analysis shows that the electron transfer in electrode reaction is quasi-reversible. CCDC: 650387. |
| Keywords: copper(Ⅱ) complex crystal structure electrochemical property |
| |
| 摘要点击次数: 1423 |
| 全文下载次数: 1568 |
| 李昶红,何晓梅,杨颖群,李 薇.配合物Cu(3，5-DMBA)2(phen)的合成、晶体结构及电化学性质[J].无机化学学报,2007,23(8):1449-1452. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
