Fe3O4/N-异丙烯酰胺(PNIPAM)纳米颗粒的合成
Synthesis of Fe3O4/Poly(N-isopropylacrylamide)(PNIPAM) Nanoparticles
作者单位
仲 慧 江苏省低维材料化学重点建设实验室淮阴师范学院化学系淮安 223300 
张莉莉 江苏省低维材料化学重点建设实验室淮阴师范学院化学系淮安 223300 
张维光 江苏省低维材料化学重点建设实验室淮阴师范学院化学系淮安 223300 
王宝珠 江苏省低维材料化学重点建设实验室淮阴师范学院化学系淮安 223300 
朱玉兰 江苏省低维材料化学重点建设实验室淮阴师范学院化学系淮安 223300 
摘要: 
关键词: 温敏  核壳  纳米颗粒  磁性物质
基金项目: 
Abstract: A magnetic and thermosensitive poly(N-isopropylacrylamide)(PNIPAM) nanoparticles were prepared by the following procedure. The core-shell composite microparticles were synthesized by precipitating polymerization with Fe3O4 being entrapped with SiO2 as core and cross-linked PNIPAM as shell. Then, the SiO2 core was etched by hydrofluoric acid and magnetic thermosensitive Fe3O4/PNIPAM particles were formed. It has also been shown that the Fe3O4/PNIPAM nanoparticles are featured by lower critical solution temperature (LCST) at 33.0 ℃ while the temperature varies from 28.0 ℃ to 36.0 ℃. The composite magnetic thermosensitive particles were characterized by XRD, SEM, TEM and FTIR. The synthetic mechanism is also discussed.
Keywords: thermosenitive  core-shell  nanoparticles  magnetic material
 
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仲 慧,张莉莉,张维光,王宝珠,朱玉兰.Fe3O4/N-异丙烯酰胺(PNIPAM)纳米颗粒的合成[J].无机化学学报,2007,23(8):1457-1462.
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