| 含NS和NNSS供电子原子的钌(Ⅲ)席夫碱配合物:催化性能和抗微生物活性（英文） | |
| Catalytic and Antimicrobial Studies of Ruthenium(Ⅲ) Schiff Base Complexes Containing NS and NNSS Donor Atoms | |
| 摘要: 通过[RuX3(EPh3)3] 或 [RuBr3(PPh3)2(MeOH)] (式中X=Cl或Br; E=P或As)与适当的席夫碱以1∶1的物质的量的比反应合成了[RuX2(L′)(EPh3)2]或[RuX(LL′)(PPh3)](式中L′=席夫碱配体1，即[S-benzyl | |
| 关键词: 钌(Ⅲ)配合物 羰基氧 顺磁性 黏土催化剂 硫 | |
| 基金项目: | |
| Abstract: Ruthenium(Ⅲ) complexes of the type [RuX2(L′)(EPh3)2] and [RuX(LL′)(EPh3)] (where， X=Cl or Br; E=P or As; L′-Schiff base ligand 1 [S-benzyl-β-N-(methyl，acetyl)methylenedithiocarbazate]， LL′-Schiff base ligand 6 [Bis(S-benzyl-β-N-(methyl)methylenedithiocarbazate]) has been synthesized by the reactions of [RuX3(EPh3)3] or [RuBr3(PPh3)2(MeOH)] with appropriate Schiff bases in 1:1 molar ratio. The Schiff base ligands (1 and 6) were prepared by condensing S-benzyldithiocarbazate (NH2NHCSSCH2C6H5) with 2，3-butanedione (1∶1 and 1∶2 molar ratio). Complexes have been characterized by analytical， spectroscopic (IR， UV-Visible， and EPR) and Cyclic voltammetric methods. The ruthenium(Ⅲ) complexes are paramagnetic and an octahedral structure has been tentatively proposed for all the new complexes. Catalytic activity of these complexes has been explored by means of a probe reaction of the acetaldehyde with H2O2. The ligands and the complexes were screened for antimicrobial activity against four organisms. | |
| Keywords: ruthenium(Ⅲ) keto oxygen paramagnetic clay catalyst sulphur | |
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| Daniel Thangadurai. T,Son-Ki Ihm.含NS和NNSS供电子原子的钌(Ⅲ)席夫碱配合物:催化性能和抗微生物活性（英文）[J].无机化学学报,2007,23(9):1515-1522. | |
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