纳米镍-铁合金/膨胀石墨复合材料的制备、表征及其电磁屏蔽性能
Preparation and Characterization of the Nano-particles Composites of Ni-Fe Alloys Dispersed on Expanded Graphite for the Shielding of Electromagnetic Radiations
作者单位
刘兰香 南京大学化学化工学院南京 210093 
黄玉安 南京大学化学化工学院南京 210093 
黄润生 南京大学物理系南京 210093 
唐 涛 南京大学物理系南京 210093 
徐 铮 南京大学化学化工学院南京 210093 
葛 欣 南京大学化学化工学院南京 210093 
沈俭一 南京大学化学化工学院南京 210093 
摘要: 
关键词: 膨胀石墨  金属纳米颗粒  铁镍合金  电磁屏蔽
基金项目: 
Abstract: The composites with nano-particles of Ni-Fe alloys dispersed on the nano-layers of expanded graphite (EG) were prepared by the impregnation of EG with ethanol solutions of nickel and iron acetates, followed by drying and reduction in H2. The square nano-particles of Ni-Fe alloys with particle sizes of mainly 20~40 nm were found to be well spread on the layers of EG. The alloy nano-particles exhibited high shielding effectiveness (SE) for electromagnetic radiations at low frequencies due to their high magnetic conductivity. Since EG is electronically conductive and displayed high SE at high frequencies, the composites exhibited good SE at wide range of frequencies. The electric and magnetic conductivities of the composites could be monitored through regulating the loadings of alloy nano-particles on EG, and it was found that the composites with 20%~40% of the alloys exhibited good SE. Specifically, the composite 27%Ni-3%Fe-EG showed the excellent SE from 66 to 110 dB at the frequencies from 300 kHz to 1.5 GHz.
Keywords: expanded graphite  metallic nano-particle  Ni-Fe alloy  shielding effectiveness
 
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刘兰香,黄玉安,黄润生,唐 涛,徐 铮,葛 欣,沈俭一.纳米镍-铁合金/膨胀石墨复合材料的制备、表征及其电磁屏蔽性能[J].无机化学学报,2007,23(9):1667-1670.
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