| 配合物{Mn(phen)2(H2O)[C8H11O2(COO)]}·(ClO4)·H2O的水热合成、晶体结构及热重分析 |
| Hydrothermal Synthesis， Crystal Structure and Thermal Stability of Complex {Mn(phen)2(H2O)[C8H11O2(COO)]}·(ClO4)·H2O |
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| 摘要: |
| 关键词: 锰(Ⅱ)配合物 水热合成 晶体结构 热重分析 |
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| Abstract: Complex {Mn(phen)2(H2O)[C8H11O2(COO)]}·(ClO4)·H2O with bicycle[2.2.1]hept-2-en-5，6-dicarboxylic acid [C7H8(COOH)2]， perchlorate manganese and 1，10-phenanthroline(phen) has been synthesized by means of hydrothermal way and characterized. It crystallizes in the triclinic space group P1， with a=1.022 08(12) nm， b=1.241 49(14) nm， c=1.354 29(15) nm， α=112.724(9)°， β=91.173(6)°， γ=101.250(3)°， V=1.545 9(3) nm3， Dc=1.553 g·cm-3， Z=2， F(000)=744. Final R1=0.042 2， wR2=0.101 5. GooF=1.080， The crystal structure shows that the cadmium ion is coordinated with one oxygen atoms from one C7H10(COOH)2 molecule， four nitrogen atoms from the two 1，10-phenanthroline， one oxygen atom from one water molecule， respectively， forming a distorted octahedral coordination geometry. The result of TG analysis shows that the title complex was stable under 200.0 ℃. CCDC: 653822. |
| Keywords: manganese(Ⅱ) complex hydrothermal synthesis crystal structure thermal stability analysis |
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| 李昶红,李 薇,杨颖群,李东平.配合物{Mn(phen)2(H2O)[C8H11O2(COO)]}·(ClO4)·H2O的水热合成、晶体结构及热重分析[J].无机化学学报,2007,23(9):1671-1674. |
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