| 含八齿苦味酸根的超分子苦味酸钾的合成和结构(英文) |
| Synthesis and Crystal Structure of Supramolecular Potassium Picrate Bearing Octadentate μ-Picrate Bridges |
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| 摘要: |
| 关键词: 钾(Ⅰ)配合物 合成 晶体结构 |
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| Abstract: A supramolecular complex， [Kpic]n (pic- is picratol， (NO2)3C6H2O-)， has been synthesized unexpectedly in acetone solution， and characterized by elemental analysis， IR and X-ray crystallography. In the complex， the K+∶pic- is 1∶1， and one K(Ⅰ) ion is surrounded by six picrate anions， one picrate anion can coordinate to six K(Ⅰ) ions. The coordination number of every potassium atom is eight. Interestingly， the picratol adopts an eight-coordinated ideal mode unreported. CCDC: 630627. |
| Keywords: potassium(Ⅰ) complex synthesis crystal structure |
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| 董文魁,宋学琴,孙银霞,吴辉禄.含八齿苦味酸根的超分子苦味酸钾的合成和结构(英文)[J].无机化学学报,2007,23(10):1809-1811. |
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