通过β-FeOOH纳米棒无序聚集制备α-Fe2O3中空球
Preparation of α-Fe2O3 Hollow Spheres via Random Aggregation of β-FeOOH Nanorods
作者单位
俞海云 安徽省金属材料与加工重点实验室安徽工业大学材料科学与工程学院马鞍山 243002
山东大学化学学院济南 250100 
陈国柱 山东大学化学学院济南 250100 
孙思修 山东大学化学学院济南 250100 
印志磊 山东大学化学学院济南 250100 
宋新宇 山东大学化学学院济南 250100 
摘要: 
关键词: 氧化铁  氧化氢氧化铁  中空  溶剂热  无序聚集
基金项目: 
Abstract: The α-Fe2O3 hollow spheres have been synthesized through the random aggregation of β-FeOOH nanorods in the C2H5OH/H2O system. The phase transformation and the morphologies of the α-Fe2O3 hollow structure were investigated with XRD, SEM, TEM and selected area electron diffraction (SAED). These studies indicate that the second step is a dissolution-recrystallization process. Furthermore, the formation mechanism of the hollow spheres has been discussed. It is found that the presence of H2O in the reaction system is essential to the final formation of the hollow spheres.
Keywords: α-Fe2O3  β-FeOOH  hollow  solvent-thermal  random aggregation
 
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俞海云,陈国柱,孙思修,印志磊,宋新宇.通过β-FeOOH纳米棒无序聚集制备α-Fe2O3中空球[J].无机化学学报,2007,23(12):2115-2118.
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