| 一种含阻转异构体的二羧酸铀(Ⅵ)有机-金属配合物(英文) |
| Uranium(Ⅵ) Metal-organic Framework with Atropisomeric Dicarboxylic Ligand |
|
| 摘要: |
| 关键词: 铀(Ⅵ)配合物 水热合成 晶体结构 |
| 基金项目: |
| Abstract: Uranium(Ⅵ) complex [UO2((R，S)-1，1′-binaphthylene-2，2′-dicarboxylate)(H2O)] was obtained by the hydrothermal treatment of UO2(NO3)2·6H2O with (R，S)-1，1′-binaphthylene-2，2′-dicarboxylic acid(BCA) (L) in water at 180 ℃ in Pyrex tube. The crystal belongs to monoclinic system， space group C2/c， with a=1.640 3(3) nm， b=1.196 7(2) nm， c=1.066 3(17) nm， β=104.412(4)°， V=2.027 2(6) nm3， Z=4. CCDC: 659617. |
| Keywords: uranium(Ⅵ) complex hydrothermal treatment crystal structure |
| |
| 摘要点击次数: 1084 |
| 全文下载次数: 1567 |
| 瞿志荣.一种含阻转异构体的二羧酸铀(Ⅵ)有机-金属配合物(英文)[J].无机化学学报,2007,23(12):2126-2127. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
