无机-高分子-无机多组分核壳纳米复合材料的制备和表征
Preparation and Characterization of Inorganic-Polymer-Inorganic Multicomponent Core-Shell Nanocomposite Material
作者单位
朱冬妹 南京大学配位化学国家重点实验室化学化工学院南京 210093 
王 飞 南京大学配位化学国家重点实验室化学化工学院南京 210093 
韩 敏 南京大学配位化学国家重点实验室化学化工学院南京 210093 
李红变 南京大学配位化学国家重点实验室化学化工学院南京 210093 
徐 正 南京大学配位化学国家重点实验室化学化工学院南京 210093 
摘要: 
关键词: 聚甲基丙烯酸甲酯  N-异丙基丙烯酰胺  四氧化三铁  银纳米粒子  复合材料
基金项目: 
Abstract: Fe3O4 nanoparticles were prepared by chemical co-precipitation using palmitic acid as surfactant, then a uniformly dispersed system of Fe3O4@Polymethylmethacrylates(PMMA) core-shell structure was obtained. Furtherm-ore, polymethylmethacrylates(PNIPAM) was encapsulated on the surface of the Fe3O4@PMMA core-shell nano-structure to get Fe3O4@PMMA@PNIPAM double shell-core composite structure. After that, the Ag nano-particles were assembled on the surface of Fe3O4@PMMA@PNIPAM taking advantage of coordination reaction between Ag+ and nitrogen atom on the amide group of PNIPAM. The magnetism of composites is convenient for the catalyst separation from the solution.
Keywords: polymethylmethacrylates  poly(N-isopropylacrylamide  Fe3O4  Ag nanoparticles  composite materials
 
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朱冬妹,王 飞,韩 敏,李红变,徐 正.无机-高分子-无机多组分核壳纳米复合材料的制备和表征[J].无机化学学报,2007,23(12):2128-2132.
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