| 一种铀(Ⅵ)配合物的水热合成、结构与性质(英文) |
| Hydrothermal Synthesis, Structure and Fluorescent Property of a Coordination Compound of Uranyl(Ⅵ) |
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| 摘要: |
| 关键词: 铀酰配合物 水热合成 晶体结构 荧光 |
| 基金项目: |
| Abstract: UO2(EPC)2 (EPC=5-ethyl-3-pyridinecarboxylate) was synthesized by the hydrothermal reaction of UO2(NO3)2 ·6H2O with imazethapyr [2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl)-5-ethyl-3-pyridine-carboxylic acid] at 120 ℃, which 2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl group was removed under this condition to result in the formation of 5-ethyl-3-pyridinecarboxylate ligand (EPC). The structure and fluorescent property of the synthesized complex is also reported. CCDC: 645641. |
| Keywords: uranyl(Ⅵ) complex hydrothermal synthesis crystal structure fluorescence |
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| 金杨波,胡 斌,李永绣,王国喜.一种铀(Ⅵ)配合物的水热合成、结构与性质(英文)[J].无机化学学报,2008,24(1):138-140. |
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