具有绿色荧光发射效应的氟喹诺酮-铀(Ⅵ)配合物(英文)
Uranium(Ⅵ) Complex Based on a Fluoroquinolone Ligand with Green Fluorescent Emission
作者单位
瞿志荣 东南大学化学化工学院南京 210096 
摘要: 
关键词: 铀(Ⅵ)配合物  水热合成  晶体结构  荧光性质
基金项目: 
Abstract: A uranium(Ⅵ) complex [UO2(1-ethyl-6,8-difluoro-7-(3-methyl-piperazinium-1-yl)-4-oxo-1,4-dihydro-quin-oline-3-carboxylate)(NO3)2] was obtained by the hydrothermal treatment of UO2(NO3)2·6H2O with lomefloxacin-HCl in water at 80 ℃ in Pyrex tube. The crystal belongs to monoclinic system, space group P21/c, with a=1.430(3) nm, b=1.032 1(18) nm, c=1.729(3) nm, β=106.67(3)°, V=2.458(6) nm3, Z=4. This complex is a good green fluorescent material in solid state at room temperature. CCDC: 660959.
Keywords: uranium(Ⅵ) complex  hydrothermal synthesis  crystal structure  fluorescence
 
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瞿志荣.具有绿色荧光发射效应的氟喹诺酮-铀(Ⅵ)配合物(英文)[J].无机化学学报,2008,24(2):316-318.
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