| H键连接的三维超分子化合物[M(H2O)6](HL)2的合成、表征与结构[H2L=1-(4-羟基苯)-5-四氮唑硫乙酸，M=MnⅡ，CoⅡ，NiⅡ，ZnⅡ](英文) |
| Supramolecular Compounds with Three-dimensional Hydrogen-bonded Network [M(H2O)6](HL)2 (H2L=1-(4-Hydroxyphenyl)-5-thioacetatetetrazole, M=MnⅡ, CoⅡ, NiⅡ and ZnⅡ): Synth |
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| 摘要: 利用配体1-(4-羟基苯)-5-巯基四氮唑(H2L)和金属盐酸盐在水溶液中反应，合成了4种离子型化合物，并测定了它们的晶体结构。分析结果显示它们是异质同晶，都属于P1空间群，分子通式为[M(H2O)6](HL)2[M=MnⅡ (1)，CoⅡ (2)，NiⅡ (3)，ZnⅡ (4 |
| 关键词: 1-(4-羟基苯)-5-巯基四氮唑 超分子化合物 氢键 π-π堆积作用 晶体结构 |
| 基金项目: |
| Abstract: The reactions of several divalent transition metals with 1-(4-Hydroxyphenyl)-5-thioacetatetetrazole (H2L) were studied in aqueous solution. MnⅡ, CoⅡ, NiⅡ, and ZnⅡ produced ionic products of general formula [M(H2O)6](HL)2. The four compounds were characterized by crystallographic methods. And the results have shown that their crystals are isostructural and belong to the triclinic P1 space group. The metal center in each compound is six-coordinated, forming an ideal octahedral geometry. These neutral formula units make unique three-dimensional supramolecular architectures through hydrogen bonding (M-OH2…O-C) and offset-panel π-π stacking interactions and stabilized by electrostatic force. CCDC: 662589, 1; 662590, 2; 662591, 3; 662592, 4. |
| Keywords: MⅡ compounds supramolecular compounds hydrogen bonds π-π stacking interactions crystal structure |
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| 张曙光,冯云龙,温一航.H键连接的三维超分子化合物[M(H2O)6](HL)2的合成、表征与结构[H2L=1-(4-羟基苯)-5-四氮唑硫乙酸，M=MnⅡ，CoⅡ，NiⅡ，ZnⅡ](英文)[J].无机化学学报,2008,24(4):581-585. |
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