| 层状钴氧化物Bi2-xAgxSr2Co2O8-δ的高温热电性能及XPS研究(英文) |
| High-temperature Thermoelectric Properties and X-ray Photoemission Spectra of Layered Co-based Oxides Bi2-xAgxSr2Co2O8-δ |
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| 摘要: 采用固相反应法制备了组成为Bi2-xAgxSr2Co2O8-δ(x=0.0, 0.4, 0.8，略写为BAC-222)的层状钴氧化物陶瓷。利用X-射线光电子能谱考察该类化合物的电子结构，结果表明钴离子以Co3+和Co4+混合价态形式存在，nCo4+/nCo3+的比例随着Ag掺杂的量增加而增加。O1s光电子谱显示在所有样品中均存在点阵氧和吸附氧。热电性能测试结果显示，随着Ag掺杂量的增加，电导率显著增加而Seebeck系数几乎保持不变，Ag的引入极大的影响了BAC-222的电子输运性质，其功率因子在1 123 K时达到了1.23×10-4 W·m-1·K-2，是一种具有很好应用前景的热电材料。 |
| 关键词: 层状钴氧化物陶瓷 热电 XPS BC-222 |
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| Abstract: Layered Co-based ceramics with a nominal composition of Bi2-xAgxSr2Co2O8-δ(x=0.0, 0.4, 0.8, denoted by BAC-222) were prepared using conventional solid state reaction method. X-ray photoemission spectroscopy(XPS) was used to investigate their electronic structures. The cobalt ions are existed in mixed states of Co3+ and Co4+. It is found that the nCo4+/nCo3+ ratio increases with the Ag doping content. The O1s photoemission spectra show that there are lattice oxygen and chemical absorbed oxygen in all the samples. Meanwhile, the conductivity and Seebeck coefficient of Bi2-xAgxSr2Co2O8-δ were studied. The substitution of Bi3+ by Ag+ results in dramatically increase of the electrical conductivity while the Seebeck coefficient is kept almost unchanged. This abnormal phenomenon means that Ag+ ions play an important role in the electrical transport property of BAC-222. The power factor of Bi1.6Ag0.4Sr2Co2O8-δ reaches 1.23×10-4 W·m-1·K-2 at 1 123 K, which suggests that Bi2-xAgxSr2Co2O8-δ are good potential oxides for thermoelectric application. |
| Keywords: layered Co-based ceramic thermalelectric XPS BC-222 |
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| 李中华,陈 刚,裴 健,刘璞生.层状钴氧化物Bi2-xAgxSr2Co2O8-δ的高温热电性能及XPS研究(英文)[J].无机化学学报,2008,24(6):926-930. |
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