| 含硫多吡啶配体及其过渡金属配合物的合成、表征与结构 |
| Syntheses, Characterization and Structures of Transition Metal Complexes with a Polypyridyl Ligand Bearing S-donors |
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| 摘要: 本文报道1个含硫多吡啶配体5，5′-二(2-吡啶硫)甲基-2，2′-联吡啶(L)及其3个过渡金属配合物{[AgL](ClO4)}∞ (1)，[CuLCl2] (2)和[Mn(L)3](ClO4)2(H2O)0.5 (3)的合成及结构表征 |
| 关键词: 含硫多吡啶配体 银(Ⅰ)配合物 铜(Ⅱ)配合物 锰(Ⅱ)配合物 晶体结构 |
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| Abstract: Three transition metal complexes with a new polypyridyl ligand bearing S-donors 5,5′-bis(2-pyridylsulfanylmethyl)-2,2′-bipyridine (L), {[AgL](ClO4)}∞ (1), [CuLCl2] (2) and [Mn(L)3](ClO4)2(H2O)0.5 (3), were synthesized and structurally characterized by IR and single crystal X-ray diffraction structural analysis. 1 has a 1D chain structure, whereas 2 and 3 take mononuclear structures. The structural differences of the three complexes were attributable to the difference of metal ions. CCDC: 686045, 1; 686046, 2; 686047, 3. |
| Keywords: polypyridyl ligand bearing S-donors Ag(Ⅰ) complex Cu(Ⅱ) complex Mn(Ⅱ) complex crystal structure |
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| 胡同亮,卜显和.含硫多吡啶配体及其过渡金属配合物的合成、表征与结构[J].无机化学学报,2008,24(8):1294-1299. |
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