| C60Pt(BINAP)金属配合物的合成表征与光电性能研究 |
| Synthesis and Characterization and Photoelectric Property of Fullerene Complex C60Pt(BINAP) |
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| 摘要: 本文利用配体取代法合成了C60Pt(BINAP)新型富勒烯膦金属配合物，采用质谱、元素分析、紫外-可见吸收光谱、红外吸收光谱、光电子能谱等对该产物进行了表征，并测定了其在光化学电池中的光伏效应。光伏效应测试结果表明：在BQ/H2Q与I2/I3-介质溶液中镀层厚度为1～2 μm时，具有较好的光电转换性能，光生电压值最高达358 mV。 |
| 关键词: 富勒烯 联萘二苯膦 金属配合物 光伏效应 |
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| Abstract: A fullerene-phosphine metal complex, C60Pt(BINAP), was synthesized by ligand substitution method. The product was characterized by MS, elemental analysis, UV-Vis, IR and XPS. The photovoltaic performances of the complex was determined in the photochemistry cell. The results showed that the fullerene-phosphine metal complex exhibited high photoelectric conversion property, especially under the conditions of BQ/H2Q and I3-/I- redox couples, and 1～2 μm of thickness of the film, the maximum value of photovoltage was 358 mV. |
| Keywords: fullerene BINAP matel complexes photoelectric effection |
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| 覃世辉,吴振奕,杨绳岩,詹梦熊.C60Pt(BINAP)金属配合物的合成表征与光电性能研究[J].无机化学学报,2008,24(10):1626-1630. |
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