| 基于柔性硫醚与Cu2Br2单元二维配位聚合物的合成、结构和荧光性质(英文) |
| Synthesis, Structure and Photoluminescent Properties of the 2D Coordination Polymers Based on Cu2Br2 Unit with Flexible Thioether |
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| 摘要: |
| 关键词: 铜配位聚合物 柔性硫醚 晶体结构 荧光 |
| 基金项目: |
| Abstract: A complex [Cu2Br2(L)2]n(1) (L=bis(2-pyrimidinylthio)methane) has been synthesized and structurally characterized. Complex 1 contains dinuclear Cu2Br2 units, which are linked by ditopic L to form a 2D layer structure with a 36-membered macrometallocycle. The adjacent layers are further connected through interpyrimidyl rings C-H…N and π-π interactions to give rise to a three-dimensional supramolecular structure. Complex 1 also displays strong green solid-state photoluminescence, due to metal-to-ligand charge-transfer (MLCT) at room temperature. CCDC: 711434. |
| Keywords: copper(Ⅰ) coordination polymer flexible thioether crystal structure photoluminescence |
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| 李冬青,时文娟.基于柔性硫醚与Cu2Br2单元二维配位聚合物的合成、结构和荧光性质(英文)[J].无机化学学报,2009,25(2):364-368. |
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