| 三维配位聚合物[C4H12N2]3[PMo12O40]的合成、结构及其电化学性质(英文) |
| Synthesis, Structure and Electrochemical Properties of Three-Dimensional Complex [C4H12N2]3[PMo12O40] |
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| 摘要: |
| 关键词: 水热合成 哌嗪 电化学性质 |
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| Abstract: The title compound [C4H12N2]3[PMo12O40] was synthesized from the hydrothermal reaction and charac-terized by IR, elemental analysis and X-ray signal crystal structural analysis. The crystal of the title complex belongs to trigonal space group R3c with a=1.788 62 nm, c=2.354 3 nm, and V=6.522 62 nm3, Z=6, R1=0.038 4, wR2=0.102 0. The compound consisted of piperazine and PMo12O403-, and the structure is extended to three dimensional framework owing to the hydrogen bond between the O atoms and N atoms. The bulk-modified carbon paste electrode(APM-CPE) using this compound as modifier shows a good electrocatalytic activity toward the oxidation of ascorbic acid(AA). CCDC: 707968. |
| Keywords: hydrothermal synthesis piperazine electrochemical properties |
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| 齐艳娟,苑晓冬,田 利.三维配位聚合物[C4H12N2]3[PMo12O40]的合成、结构及其电化学性质(英文)[J].无机化学学报,2009,25(6):1110-1114. |
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