| 2-吡嗪羧酸铜配合物的合成及其结构表征(英文) | |||||||
| Synthesis and Structural Characterization of 2-Pyrazinecarboxylate Copper Compound {[Cu2(Pyz)2(H2O)4]·SO4}n (Pyz=2-pyrazinic acid) | |||||||
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| 摘要: | |||||||
| 关键词: 2-吡嗪羧酸 铜 晶体结构 配位聚合物 | |||||||
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| Abstract: Solvothermal reaction of 2-pyrazinic acid with Cu(SO4)2·5H2O yields the title complex {[Cu2(Pyz)2(H2O)4]·SO4}n(1), which was characterized by elemental analysis, IR and single crystal X-ray diffraction structural analysis. The complex 1 crystallizes in Monoclinic system, space group P21/c, with lattice parameters a=1.126 87(6) nm, b=0.073 511(4) nm, c=1.185 06(7) nm, β=95.070(2)°, and V=0.977 83(9) nm3, Z=4, Dc=2.172 Mg·m-3. CCDC: 692347. | |||||||
| Keywords: 2-pyrazinic acid copper crystal structure coordination polymer | |||||||
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| 禹良才,赖 兰.2-吡嗪羧酸铜配合物的合成及其结构表征(英文)[J].无机化学学报,2009,25(6):1137-1140. | |||||||
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