| Abstract: The title compound, [Ag4(L)4](PMBS)4·2H2O (1), where L=2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene, PMBS=p-methylbenzenesulfonate was synthesized and its crystal structure was determined by X-ray diffraction structure analysis. The crystal is of triclinic, space group P1 with a=0.820 3(2) nm, b=1.322 7(3) nm, c=2.061 0(3) nm, α=76.155(2)°, β=78.651(4)°, γ=89.993(3)°, V=2.126 2(8) nm3, Z=2, Dc=1.644 g·cm-3, F(000)=1 068, R=0.052 4, wR=0.113 6. The Ag atoms are linear coordinated by two N atoms of two L ligands, while the p-methylben-zenesulfonate molecules are included in the lattice and connected to [Ag(L)]n by hydrogen bonding interactions to form a three-dimensional supramolecular structure. CCDC: 727587. |
| 陈满生,何春梅,邓奕芳,邝代治,张春华,邓戊有.三维超分子化合物[Ag4(L)4](PMBS)4·2H2O的合成、晶体结构和荧光性质(英文)[J].无机化学学报,2009,25(7):1312-1315. |
