| 二维网状有机锑对氨基苯乙酸酯的合成、表征及晶体结构研究(英文) |
| Synthesis, Characterization and Crystal Structure of A 2D Organoantimony Complex (C6H5)3Sb(O2CCH2C6H4NH2-p)2 |
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| 摘要: |
| 关键词: 有机锑羧酸酯 对氨基苯乙酸 合成 晶体结构 |
| 基金项目: |
| Abstract: The title complex bis(4-aminophenylacetate)triphenylantimony(V) has been synthesized by the reaction of triphenylantimony dibromide with 4-aminophenylacetic acid in 1∶2 molar ratio. The complex was characterized by elemental analysis, IR spectra, NMR ( 1H, 13C) and X-ray diffraction crystal structure analysis. This complex crystallizes in the monoclinic system, space group C2/c with a=2.279 4(2) nm, b=0.957 10(10) nm, c=1.335 49(15) nm, β=93.781(2)°. The molecular structure adopts a distorted trigonal bipyramidal geometry around the antimony atom. In the crystal structure molecules are connected by intermolecular N-H…O hydrogen-bonding interactions forming a two-dimensional network structure. CCDC: 726039. |
| Keywords: organoantimony carboxylate 4-aminophenylacetic acid synthesis crystal structure |
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| 温丽媛,尹汉东,王大奇.二维网状有机锑对氨基苯乙酸酯的合成、表征及晶体结构研究(英文)[J].无机化学学报,2009,25(8):1470-1473. |
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