| 具有一维孔道的配位聚合物[{NaCd4(IDC)3(prz)}·3H2O]n的合成、晶体结构及性质研究(英文) |
| Synthesis, Crystal Structure and Luminescent Properties of Coordination Polymer [{NaCd4(IDC)3(prz)}·3H2O]n with 1D Channels |
|
| 摘要: 通过水热方法，采用H3IDC(H3IDC=imidazole-4，5-dicarboxylic acid)、prz (prz=piperazine)与Cd(NO3)2·4H2O反应，合成了具有一维孔道的配位聚合物[{NaCd4(IDC)3(prz)}·3H2O]n (1)，并对其结构和荧光性质进行了研究。结构分析结果表明该化合物属于单斜晶系，Cc空间群。其结构单元中含有4个独立的Cd原子。3个Cd原子形成一个小环，6个Cd原子形成一个大环。这些环通过IDC3-和Cd(Ⅱ)的配位作用，进一步连接产生了含一维孔道的配位聚合物。孔道内含有大量水分子和Na+离子。研究表明，该配合物在室温下能发出很强的兰色荧光。 |
| 关键词: 孔洞结构 配位聚合物 一维孔道 荧光性质 |
| 基金项目: |
| Abstract: A 3D coordination polymer with 1D channels of [{NaCd4(IDC)3(prz)}·3H2O]n(1) (H3IDC=imidazole-4,5-dicarboxylic acid, prz=piperazine) was hydrothermally synthesized, and characterized by single-crystal X-ray diffraction. The crystal belongs to monoclinic system, space group Cc. There are four crystallographically independent Cd(Ⅱ) ions in the crystal lattice. Three Cd(Ⅱ) atoms form a small ring, and six Cd(Ⅱ) atoms form a large ring. The rings are further connected by the coordination interactions of IDC3- and Cd(Ⅱ) to generate a novel 3D frameworks containing 1D hexagonal channels, which is occupied by water molecules and Na+ ions. The compound displays strong blue fluorescent emission at room temperature. CCDC: 688709. |
| Keywords: porous structure coordination polymer 1D channel luminescent properties |
| |
| 摘要点击次数: 1766 |
| 全文下载次数: 2052 |
| 顾金忠,高竹青,窦 伟,谭民裕.具有一维孔道的配位聚合物[{NaCd4(IDC)3(prz)}·3H2O]n的合成、晶体结构及性质研究(英文)[J].无机化学学报,2009,25(9):1663-1667. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
