| 两个双四唑胺的铜配合物的合成、结构及荧光性质(英文) |
| Synthesis, Crystal Structures and Fluorescent Properties of Two Cu2+ Supramolecular Complexes with H2bta Ligand |
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| 摘要: 用Demko-Sharpless方法自制的双四唑胺配体，再混以乙二胺和丙二胺螯合配体，合成了2个新颖的铜的配合物Cu(bta)(en)(H2O) (1)与Cu(bta)(1，3-pda)(H2O) (2)。X-射线单晶衍射表征了2个配合物的结构。2个配合物的水溶液都表现出了双四唑胺配体的特征吸收波长与荧光发射波长。 |
| 关键词: 双四唑胺 铜配合物 结构 荧光性质 |
| 基金项目: |
| Abstract: Two copper complexes Cu(bta)(en)(H2O) (1) and Cu(bta)(pn)(H2O) (2) (H2bta=bis(tetrazoly)amine) with H2bta ligand have been synthesized and structurally characterized by single crystal X-ray diffraction structural analysis. The aqueous solution of 1 and 2 show interesting fluorescent properties caused by H2bta ligand at room temperature. CCDC: 715563, 1; 715564, 2. |
| Keywords: H2bta Cu2+ complex crystal fluorescent property |
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| 管阳凡,周爱菊,王东耀,董 文.两个双四唑胺的铜配合物的合成、结构及荧光性质(英文)[J].无机化学学报,2010,26(2):318-322. |
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