| 基于1，5，9-三硒杂[9]二茂铁环蕃的一维链状汞(Ⅱ)配位聚合物的合成与晶体结构(英文) |
| Synthesis and Crystallographic Study of 1D Mercury(Ⅱ) Coordination Polymer of 1,5,9-Triselena[9]ferrocenophane |
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| 摘要: |
| 关键词: 汞(Ⅱ) 1，5，9-三硒杂[9]二茂铁环蕃 配位聚合物 |
| 基金项目: |
| Abstract: A mercury(Ⅱ) coordination polymer with 1,5,9-triselena[9]ferrocenophane (L), [HgI2L·0.5C4H4O·0.5CH3OH]n, has been synthesized and characterized. The X-ray crystal structure shows that bridging by the ligand L causes compound to form one-dimensional chain. The half-wave potential of 1,1′-ferrocenylene group is more negative than that of the “free” ligand, which reveals no through-space interaction Hg…Fe in the coordination polymers. CCDC: 742585. |
| Keywords: Mercury(Ⅱ) 1,5,9-Triselena[9]ferrocenophane coordination polymer |
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| 顾诚云,景 苏,杨 波,魏 烨,张 文,吉 玮.基于1，5，9-三硒杂[9]二茂铁环蕃的一维链状汞(Ⅱ)配位聚合物的合成与晶体结构(英文)[J].无机化学学报,2010,26(2):339-342. |
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