| [U(CO3)3(H2O)2]·2H2O配合物的合成及晶体结构(英文) |
| Synthesis and Crystal Structure of a Uranylcontaining Complex [U(CO3)3(H2O)2]·2H2O |
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| 摘要: |
| 关键词: 铀 晶体结构 碳酸根 |
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| Abstract: A uranylcontaining compound [U(CO3)3(H2O)2]·2H2O has been synthesized under hydrothermal condition and characterized by X-ray single-crystal analysis. Crystal structural analysis indicates that this compound consists of three CO32- molecules, one U6+. The results reveal that the title compound presents a 3D frame work built up by O-H…O week hydrogen bonds interactions. The central uranium atom is eight-coordinated through three CO32- molecules and two H2O. The compound shows a coplanar hexagonal network structure, each hexagon containing a hexagonal hole with a water moleculet. CCDC: 737313. |
| Keywords: uranium crystal structure carbonate |
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| 王 娟,吕 鑫,李子颖,张玉燕,程时远.[U(CO3)3(H2O)2]·2H2O配合物的合成及晶体结构(英文)[J].无机化学学报,2010,26(2):351-354. |
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