| Co2+掺杂的纳米TiO2薄膜光催化特性及电化学阻抗谱研究 |
| The Photocatalytic Properties and Electrochemical Impedance Spectroscopy of Co2+ Doped TiO2 Thin Film |
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| 摘要: 本文采用交流电沉积技术, 在多孔氧化铝模板中合成出Co2+掺杂的纳米TiO2薄膜(Co2+/TiO2薄膜)。以次甲基蓝为降解物，研究了纳米Co2+/TiO2薄膜在可见光下的催化性能，考察了阳极偏压对光催化活性的影响。用电化学阻抗谱(EIS)研究了纳米Co2+/TiO2薄膜在次甲基蓝溶液中的电化学行为，给出了相应的等效电路和半导体能带结构参数-空间电荷层宽度。研究表明，适量Co2+掺杂可以提高TiO2薄膜的光催化活性。在Co2+/TiO2膜电极上施加一定阳极偏压，使空间电荷层宽度增加，因此能有效实现光生电子-空穴分离，进一步提高次甲基蓝的光催化降解效率。 |
| 关键词: Co2+掺杂的TiO2薄膜 光催化 阳极偏压 电化学阻抗谱 |
| 基金项目: |
| Abstract: The Co2+ doped nano-TiO2 thin film(Co2+/TiO2 thin film) was prepared by the A.C. electrodeposition method into porous alumina temple. The photocatalytic property of the nano-Co2+/TiO2 thin film was evaluated by degradation of methylene blue under visible light irradiation, and the effect of anode bias on photocatalytic activity was investigated. The electrochemical behavior of nano-Co2+/TiO2 thin film was investigated by means of Electrochemical Impedance Spectra (EIS) in methylene blue solutions, relevant equivalent circuit and the band structure parameter-the width of space charge layer were also presented . The results show that Co2+ doping can improve the photocatalytic activity of nano-TiO2 thin film．When an anode bias was applied on the nano-Co2+/TiO2 thin film, the width of space charge layer increased than without the bias, suggesting more efficient separation of photogenerated electron-hole pairs, the degradation efficiency of methylene blue can be greatly increased. |
| Keywords: Co2+ doped TiO2 thin film photocatalysis anode bias Electrochemical Impedance Spectroscopy(EIS) |
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| 梁燕萍,贾剑平,吕向菲,吴振森,史启祯.Co2+掺杂的纳米TiO2薄膜光催化特性及电化学阻抗谱研究[J].无机化学学报,2010,26(4):633-638. |
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