| 新型一维钼氧链超分子化合物[(H2bpe)Mo4O13]的合成与光学性质研究(英文) |
| Hydrothermal Synthesis, Characterization and Luminescence Property of a New 1D Molybdenum Oxide Chain: [(H2bpe)Mo4O13] |
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| 摘要: |
| 关键词: 钼氧链 晶体结构 光学性质 |
| 基金项目: |
| Abstract: A new 1D compound [(H2bpe)Mo4O13](1) (bpe=trans-1,2-Di-(4-pyridyl)-ethylen) was hydrothermally synthesized and characterized. Compound 1 comprises 3D supramolecular network constructed from 1D [Mo4O13]2- anion chains and protonated bpe layers via hydrogen bonds and π-π stacking interactions. The crystal data are the following: C12H12Mo4N2O13, Monoclinic, space group P21/n, a=0.968 64(13) nm, b=1.349 68(18) nm, c=1.514 9(2) nm, β=99.766(2)°, Z=4. The inorganic chain built up from only molybdenum oxide building blocks is interesting. The luminescent property of 1 was studied. CCDC: 739954. |
| Keywords: molybdenum oxide chain crystal structure luminescent property |
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| 吴晶晶,韩占刚,王彦娜,郝青华,翟学良.新型一维钼氧链超分子化合物[(H2bpe)Mo4O13]的合成与光学性质研究(英文)[J].无机化学学报,2010,26(5):921-925. |
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