| 一个双螺旋配合物[Cd2L2(2，2′-bipy)2]n的合成、晶体结构与荧光性质(英文) |
| Synthesis, Crystal Structure and Luminescent Property of a New Double Helix Complex [Cd2L2(2，2′-bipy)2]n |
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| 摘要: |
| 关键词: 1，4-苯二硫乙酸 晶体结构 双螺旋结构 荧光 |
| 基金项目: |
| Abstract: A flexible carboxylic ligand, 1,4-benzenebis(thioacetic acid) (H2L), has been employed to assemble with Cd(Ⅱ) ions under hydrothermal conditions, generating a new complex [Cd2L2(2，2′-bipy)2]n(1). X-ray diffraction reveals the complex 1 possesses a self-assembly double helix structure deriving from [Cd2L2(2,2′-bipy)2] units linked by L2- ligands. A 3D infinite framework is constructed via π-π stacking of 2,2′-bipy. The photoluminescent properties in solid state were investigated. CCDC: 705078. |
| Keywords: 1,4-benzenebis(thioacetic acid) crystal structure double helix structure luminescent property |
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| 陈 静,尹建玲,王晓娟,冯云龙.一个双螺旋配合物[Cd2L2(2，2′-bipy)2]n的合成、晶体结构与荧光性质(英文)[J].无机化学学报,2010,26(7):1311-1314. |
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