| 铜(Ⅱ)与2-吡啶酸、4，4′-联吡啶配合物的合成、结构和电化学性质(英文) |
| Synthesis, Crystal Structure and Cyclic Voltametric Property of Cu(Ⅱ) Complex with 4,4′-Bipy and α-Pyridine Carboxylate |
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| 摘要: |
| 关键词: Cu(Ⅱ)配合物 4，4′-联吡啶 晶体结构 循环伏安 |
| 基金项目: |
| Abstract: The complex [Cu(bipy)(pc)(H2O)(ClO4)]·H2O (1) (bipy: 4,4′-bipyridine; Hpc: α-pyridine carboxylic acid) has been synthesized and characterized by single crystal X-ray diffraction method and elemental analysis. It crysrallizes in the Monoclinic space group P21/n. The crystal structure reveals that Cu(Ⅱ) centre adopts a pseudo octahedral geometry. Ligand 4,4′-bipyridine as a bridge coordinates to two different Cu(Ⅱ) center to form a one-dimensional zigzag chain. One dimensional chains are linked by C-H…O hydrogen bonding interactions to form two-dimensional layer. Layers are connected by O…H-O hydrogen bond to generate three-dimensional structure. The cyclic voltametric behavior of complex 1 is also investigated. CCDC: 743537. |
| Keywords: copper(Ⅱ) complex 4,4′-bipyridine cyclic voltametry |
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| 摘要点击次数: 1568 |
| 全文下载次数: 1901 |
| 吴 刚,王小锋,鲜 华,郭学林.铜(Ⅱ)与2-吡啶酸、4，4′-联吡啶配合物的合成、结构和电化学性质(英文)[J].无机化学学报,2010,26(7):1315-1318. |
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