| 三维配合物[Zn2(OH)(pyim)(BIPA)]n的水热合成、晶体结构和荧光性质研究(英文) |
| Hydrothermal Synthesis, Crystal Structure and Photoluminescence of a Novel Three-Dimensional Zinc(Ⅱ) Complex: [Zn2(OH)(pyim)(BIPA)]n |
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| 摘要: |
| 关键词: 锌配合物 晶体结构 多酸配体 荧光性质 |
| 基金项目: |
| Abstract: Hydrothermal reaction between 5-bromoisophthalic acid (H2BIPA) and Zn(NO3)2·6H2O at the presence of the second ligand of 2-(2-pyridyl)imidazole (Hpyim) yields a new 3D metal-organic coordination polymer [Zn2(OH)(pyim)(BIPA)]n (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IR spectrum and thermal analysis. Complex 1 presents an α-Po net with 41263 topology constructed from tetranuclear clusters and displays strong luminescent emission at room temperature. CCDC: 763940. |
| Keywords: Zinc(Ⅱ) complex crystal structure multicarboxylate ligand luminescence |
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| 刘光祥,许玉勇,黄荣谊,任小明.三维配合物[Zn2(OH)(pyim)(BIPA)]n的水热合成、晶体结构和荧光性质研究(英文)[J].无机化学学报,2010,26(8):1477-1481. |
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