| Abstract: A one-dimensional chain tri(n-butyl)tin 2,4-dichloro-phenoxy acetate has been synthesized and charact-erized by IR, 1H NMR spectra and elemental analysis.The crystal structure has been determined by X-ray diffrac-tion. The crystal belongs to monoclinic space group P21/c with a=1.350 1(8) nm, b=1.785 4(3) nm, c=1.049 2(2) nm, β=105.146(10)°, Z=4, V=2.441 4(2) nm3, Dc=1.388 Mg·m-3, μ(Mo Kα)=1.280 mm-1, F(000)=1 040, R1=0.044 2, wR2=0.121 9. In the complex, tin atoms are five-coordinated distorted trigonal bipyramid configuration with bridging 2,4-dichloro-phenoxyacetic acid carboxy. The result of analysis shows that the electron transfer in electrode reaction is irreversible. CCDC: 715238. |
| 庾江喜,邝代治,尹笃林,冯泳兰,张复兴,王剑秋,许志锋.一维链状三正丁基锡2，4-二氯苯氧乙酸酯的合成、结构和电化学性质研究[J].无机化学学报,2010,26(8):1507-1510. |
