| 一维双链镉(Ⅱ)配合物[Cd(C5H5N)CH2C(OH)(PO3)(PO3H)·3H2O]n的合成与晶体结构(英文) |
| Synthesis and Crystal Structure of a Double Chain Complex [Cd(C5H5N)CH2C(OH)(PO3)(PO3H)·3H2O]n |
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| 摘要: |
| 关键词: 镉配合物 吡啶基二膦酸 晶体结构 |
| 基金项目: |
| Abstract: A new cadmium complex [Cd(C5H5N)CH2C(OH)(PO3)(PO3H)·3H2O]n((C5H4N)CH2C(OH)(PO3H2)2=1-hydroxy-2-(2-pyridyl)ethylidene-1,1-diphosphonate acid) has been synthesized under hydrothermal conditions. Single crystal structure determination reveals that the compound has a ladder-like chain structure in which the edge-shared {CdO6} octahedra are linked by {CPO3} tetrahedra through corner-sharing. The chains of {Cd(C5H5N)CH2C(OH)(PO3)(PO3H)}n are linked by inter-chain hydrogen bonds, forming a supramolecular layer. CCDC: 722396. |
| Keywords: cadmium complex pyridyl-diphosphonate crystal structure |
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| 摘要点击次数: 1473 |
| 全文下载次数: 1978 |
| 马运声,唐晓艳,袁荣鑫.一维双链镉(Ⅱ)配合物[Cd(C5H5N)CH2C(OH)(PO3)(PO3H)·3H2O]n的合成与晶体结构(英文)[J].无机化学学报,2010,26(9):1703-1706. |
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