| Abstract: The complex [Mn(4,4′-bipy)2(H2O)4](HtsgluO)2·2H2O (H2tsglu=(+)-N-Tosyl-L-glutamic acid, 4,4′-bipy=4,4′-bipyridine) was synthesized and characterized by X-ray diffraction. The crystal structure belongs to a triclinic system , space group P1 with unit cell parameters: a=0.714 71(17) nm, b=1.372 3(3) nm, c=1.427 0(3) nm, α=66.252(3)°, β=86.692(4)°, γ=83.607(3)°, V=1.272 9(5) nm3, Z=1, Dc=1.404 g·cm-3, F(000)=563, GOF=1.044, R1=0.054 2, wR2=0.145 1 [I>2σ(I)]. The complex is constructed from two subunits, [Mn(4,4′-bipy)2(H2O)4]2+ and HtsgluO-, which is further connected by π-π stacking and hydrogen bonds interactions to form 2D supramole-cular network. CCDC: 760112. |
