| 环状二核铜配合物[Cu(nphth)(phen)(H2O)]2·2H2O的水热合成与晶体结构(英文) |
| Hydrothermal Synthesis and Crystal Structure of a Cyclic Binuclear Copper Complex [Cu(nphth)(phen)(H2O)]2·2H2O |
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| 摘要: 在水热反应条件下，合成了一个新配合物，[Cu(nphth)(phen)(H2O)]2·2H2O(nphth=3-硝基邻苯二甲酸阴离子，phen=邻菲 咯啉)，经元素分析、红外、热重、单晶衍射表征了配合物。该配合物为单斜晶系，空间群P21/n，结构参数：a=0.999 8(1) nm，b=1.044 5(1) nm，c=1.820 6(1) nm，β=91.423(1)°，V=1.900 7(2) nm3，Z=2，R=0.039 4，wR=0.096 5。结构分析表明，配合物为分立环状二核结构，并通过分子间氢键和π-π作用扩展为二维超分子网络结构。 |
| 关键词: 铜配合物 3-硝基邻苯二甲酸 水热合成 晶体结构 |
| 基金项目: |
| Abstract: A novel complex [Cu(nphth)(phen)(H2O)]2·2H2O (nphth=3-nitrophthalate, phen=1,10-phenanthroline) was synthesized by hydrothermal reaction and characterized by elemental analysis, IR, TGA and X-ray single crystal diffraction. The title complex crystallizes in monoclinic with space group P21/n, a=0.999 8(1) nm, b=1.044 5(1) nm, c=1.820 6(1) nm, β=91.423(1)°, V=1.900 7(2) nm3, Z=2, R=0.039 4, wR=0.096 5. The structure analysis shows that the complex exhibits a discrete cyclic binuclear structure. The 2D supramolecular network is constructed through hydrogen bonds and π-π interaction. CCDC: 801643. |
| Keywords: copper complex 3-nitrophthalic acid hydrothermal synthesis crystal structure |
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| 姜秀榕,温德才,董 雁,陈武华.环状二核铜配合物[Cu(nphth)(phen)(H2O)]2·2H2O的水热合成与晶体结构(英文)[J].无机化学学报,2011,27(2):393-396. |
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