| Abstract: A new copper(Ⅰ) complex has been synthesized and characterized by elemental analysis, IR, PL, TG and X-ray single crystal diffraction. The title complex crystallizes in triclinic with space group P1, a=0.811 00(16) nm, b=0.969 50(19) nm, c=1.204 9(2) nm, α=97.88(3)°, β=93.31(3)°, γ=94.14(3)° and V=0.933 8(3) nm3, Z=1, R=0.037 1. In the title complex, each Cu(Ⅰ) ion displays a triangle geometry, with one N atom from 2,4-diamino-5-(p-chlorophenyl)-6-ethyl-pyrimidine (PMN) and two iodine atoms. Two adjacent Cu(Ⅰ) ions are linked by two μ2-I atoms into a dinuclear copper(I) complex, which are further connected by intermolecular hydrogen bond (N-H…N, C-H…I) and I…I interactions to form a three-dimensional supramolecular network. Furthermore, the solid-state fluorescence property of the complex was studied at room temperature. CCDC: 794866. |
