| 一个新的粘液酸锰(Ⅱ)配合物的合成、结构与性能研究(英文) | |
| Synthesis, Crystal Structure and Properties of a New Manganese(Ⅱ) Complex with Mucic Acid | |
| 摘要: 合成了1个以粘液酸为配体的锰(Ⅱ)配合物Mn[(muc)(H2O)3]·H2O (1)，并通过红外光谱，元素分析，热重分析和X-射线单晶衍射对其进行了表征。配合物1由一维链组成，其三维网络结构可以简化为dia拓扑。初步的电化学实验表明，配合物1在电化学储能上有应用潜力，可以作为氢氧化镍电极的添加剂。 | |
| 关键词: 锰(Ⅱ)配合物 粘液酸 晶体结构 氢氧化镍电极 添加剂 | |
| 基金项目: | |
| Abstract: A new manganese complex [Mn(muc)(H2O)3]·H2O (1) (H2muc=mucic acid) has been synthesized and characterized by X-ray single-crystal diffraction, elemental analysis, IR spectrum, and thermogravimetry analysis. The structure of 1 is composed of 1D chains and further joined by hydrogen bonds to construct a 3D supramolecule structure. Preliminary electrochemical experiments indicated that as an additive on nickel hydroxide electrodes 1 could improve the electrochemical performance and has potential applications in electrochemical storage. CCDC: 720478. | |
| Keywords: manganese(Ⅱ) complex mucic acid crystal structure nickel hydroxide electrode additive | |
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| 吕耀康,冯云龙,刘继伟,詹才宏,陈 静,王晓娟,蒋战果.一个新的粘液酸锰(Ⅱ)配合物的合成、结构与性能研究(英文)[J].无机化学学报,2011,27(4):791-796. | |
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