| 二维层状锌配合物[Zn(bibm)(glu)]n的合成、晶体结构及荧光性质 |
| The Synthesis, Crystal Structure Characterization and Photoluminescent Property of 2D Layer Coordination Polymer [Zn(bibm)(glu)]n |
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| 摘要: 用水热法合成了1个新的锌配合物[Zn(bibm)(glu)]n(bibm=4，4′-二(苯并咪唑-1-甲基)联苯；glu=戊二酸)，对它进行了红外光谱、元素分析、XRD、热重和荧光等表征，并用X-射线单晶衍射法测定了配合物的单晶结构。该配合物属单斜晶系，P21/n空间群，为二维层状结构。实验结果表明该配合物具有较好的荧光性质，是潜在的荧光光学材料。 |
| 关键词: 锌配合物 晶体结构 荧光性质 |
| 基金项目: |
| Abstract: A new complex [Zn(bibm)(glu)]n based on a semi-rigid N-containing ligand bibm (bibm=4,4′-Bis(benzimidazol-1-ylmethyl)biphenyl, glu=glutaric acid) has been synthesized by hydrothermal method and characterized by IR spectra, elemental analysis, XRD, TGA, fluorescence, and the crystal structure was determined by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group P21/n, and features a two-dimensional (2D) layer structure. The experimental results show that this complex has good fluorescence property and can be used as a potential optical material. CCDC: 807083. |
| Keywords: Zn(Ⅱ) complex crystal structure fluorescence property |
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| 全文下载次数: 1968 |
| 曹大鹏,姚小强,郑和根.二维层状锌配合物[Zn(bibm)(glu)]n的合成、晶体结构及荧光性质[J].无机化学学报,2011,27(5):903-906. |
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