| 二(1-环戊烯基环戊二烯基)四羰基二钌(Ⅰ)的合成与晶体结构 | |
| Synthesis and Crystal Structure of Di(1-cyclopentenylcyclopentadienyl) Tetracarbonyl Diruthenium(Ⅰ) | |
| 摘要: 由6，6-四亚甲基富烯与Ru3(CO)12在二甲苯中加热回流，合成了一个新的双核配合物(η5-C10H11)2Ru2(CO)2(μ-CO)2。通过元素分析、红外光谱、核磁共振氢谱对其结构进行了表征，用X射线单晶衍射法测定了配合物的结构，结果表明：晶体属于三斜晶系，P1 空间群，a=0.641 57(19) nm，b=0.761 3(2) nm，c=1.192 4(3) nm，α=89.973(4)°，β=87.143(4)°，γ=69.666(4)°，V=0.545 3(3) nm3，Dc=1.756 g·cm-3，μ=1.412 mm-1，F(000)=286，Z=1，R1=0.024 0，wR2=0.066 7。晶体结构表明6，6-四亚甲基富烯在反应过程中发生了双键的异构。CCDC: 748430。 | |
| 关键词: 羰基钌 富烯 二聚物 晶体结构 X射线衍射 | |
| 基金项目: | |
| Abstract: 6,6-Tetramethylenefulvene reacted with Ru3(CO)12 in refluxing xylene to give the new dinuclear complex (η5-C10H11)2Ru2(CO)2(μ-CO)2. Its molecular structure was characterized by elemental analysis, IR, 1H NMR. X-ray crystallography of the compound reveals that it belongs to triclinic system P1 space group, with a=0.641 57(19) nm, b=0.761 3(2) nm, c=1.192 4(3) nm, α=89.973(4)°, β=87.143(4)°, γ=69.666(4)°, V=0.545 3(3) nm3, Dc=1.756 g·cm-3, μ=1.412 mm-1, F(000)=286, Z=1, R1=0.024 0, wR2=0.066 7. Its crystal structure shows that the 6,6-tetramethylenefulvene undergoes double-bond isomerization in the reaction. CCDC: 748430. | |
| Keywords: ruthenium carbonyl fulvene dimer crystal structure X-ray diffraction | |
| 摘要点击次数: 1526 | |
| 全文下载次数: 1784 | |
| 马志宏,刘晓焕,林丽枝,韩占刚,郑学忠,林 进.二(1-环戊烯基环戊二烯基)四羰基二钌(Ⅰ)的合成与晶体结构[J].无机化学学报,2011,27(5):913-916. | |
| 查看全文 查看/发表评论 下载PDF阅读器 | |
| Support information: | |
|
| |
|
| |
|
| |