| 二维双层蜂窝状锌配合物的合成、晶体结构及性质研究(英文) |
| Synthesis, Crystal Structure and Properties of 2D Bilayer Honeycomb Network Zinc(Ⅱ) Complex |
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| 摘要: 利用水热反应合成了一种新的二维双层蜂窝状锌配合物{[Zn2(atz)3(N3)]·H2O}n (1)(atz=5-氨基四氮唑)，并用元素分析，红外光谱和X-射线单晶衍射对其结构进行了表征,该配合物属单斜晶系，C2/m空间群,晶胞参数为：a=1.039 7(2) nm，b=1.792 7(4) nm，c=1.109 2(2) nm，V=1.887 0(7) nm3，Z=4。该锌配合物是由N3-和原位合成的5-氨基四氮唑阴离子构成，拓扑分析表明该化合物显示出独特的4-连接六边形的蜂窝双层结构。同时还测定了该化合物的热稳定性及荧光性质。 |
| 关键词: 锌配合物 5-氨基四氮唑 晶体结构 热稳定性 荧光性质 |
| 基金项目: |
| Abstract: A new 2D bilayer honeycomb zinc complex of {[Zn2(atz)3(N3)]·H2O}n(1) (atz=5-amino-tetrazolate), has been synthesized under the hydrothermal condition and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The crystal structure of 1 is of monoclinic, space group C2/m with a=1.039 7(2) nm, b=1.792 7(4) nm, c=1.109 2(2) nm, V=1.887 0(7) nm3, Z=4. Complex 1 is built from N3- anion and in-situ generated 5-amino-tetrazolate ligand. The topological net of 1 shows a unique four-connected hexagonal bilayer “hcb” topology (honeycomb network). Thermal stability and luminescent property of the complex have also been investigated. CCDC: 722571. |
| Keywords: zinc complex 5-amino-tetrazolate crystal structure thermal stability luminescent property |
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| 刘冬生,隋 岩,陈文通,黄长沧,陈建中.二维双层蜂窝状锌配合物的合成、晶体结构及性质研究(英文)[J].无机化学学报,2011,27(8):1607-1612. |
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