| 邻乙酰氨基苯甲酸、邻菲咯啉锌(Ⅱ)配合物的合成、晶体结构及性质研究 | |||||||||||
| Synthesis, Crystal Structure and Properties of the Zinc(Ⅱ) Complex with o-Acetamidobenzoic Acid and 1,10-Phenanthroline | |||||||||||
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| 摘要: 在甲醇水混合溶剂中，以邻乙酰氨基苯甲酸(o-ABA)，1，10-邻菲咯啉(phen)为配体与高氯酸锌合成了标题配合物[Zn(o-ABA)(phen)2](ClO4)·0.5H2O。配合物(C66H50N10O15C12Zn2，分子量为1 424.80)晶体属三斜晶系，空间群P1，晶胞参数：a=1.181 6(6) nm，b=1.635 6(8) nm，c=1.752 2(9) nm，α=95.733(9)°，β=93.083(8)°，γ=109.212(8)°；V=3.168(3) nm3，Dc=1.494 g·cm-3，Z=2，F(000)=1 460。最终偏离因子R1=0.048 2，wR2=0.098 3。晶体结构表明：锌原子与1个对乙酰氨基苯甲酸的2个氧原子，2个1，10-邻菲咯啉中的4个氮原子配位，形成六配位的变形八面体结构。并对配合物的热稳定性，光谱及电化学性质进行了分析。 | |||||||||||
| 关键词: 锌(Ⅱ)配合物 合成 晶体结构 性能研究 | |||||||||||
| 基金项目: | |||||||||||
| Abstract: The title complex has been synthesized with o-acetamidobenzoic acid and 1,10-phenanthroline(phen) in the solvent mixture of water and methanol. It crystallizes (C66H50N10O15C12Zn2, Mr=1 424.80), triclinic, space group P1 with a=1.181 6(6) nm, b=1.635 6(8) nm, c=1.752 2(9) nm, α=95.733(9)°, β=93.083(8)°, γ=109.212(8)°, V=3.168(3) nm3, Dc=1.494 g·cm-3, Z=2, F(000)=1 460, R1=0.048 2, wR2=0.098 3. The crystal structure shows that the zinc atom is coordinated with two oxygen atoms from one o-acetamidobenzoic acids molecules, four nitrogen atoms from two 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry. TG analysis, spectrum property and the cyclic voltammetric behavior of the complex was investigated. CCDC: 833353. | |||||||||||
| Keywords: zinc(Ⅱ) complex synthesis crystal structure properties study | |||||||||||
| 摘要点击次数: 2024 | |||||||||||
| 全文下载次数: 1474 | |||||||||||
| 李 薇,李昶红,杨颖群,谭雄文.邻乙酰氨基苯甲酸、邻菲咯啉锌(Ⅱ)配合物的合成、晶体结构及性质研究[J].无机化学学报,2011,27(10):1919-1923. | |||||||||||
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