| 5-氨基双四唑富氮配位化合物的合成、结构及其对高氯酸铵的热分解影响(英文) |
| Nitrogen-Rich Coordination Compounds with N,N-Bis(1H-tetrazole-5-yl)-amine: Synthesis, Structure and Effect on the Thermal Decomposition of Ammonium Perchlorate |
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| 摘要: 水热条件下合成了两个5-氨基双四唑配位化合物Cu(bta)(bpy)(H2O) (1)和Pb2(bta)2(en)2·4H2O (2)(H2bta=5-氨基双四唑，bpy=2,2′-联吡啶，en=乙二胺)，并借助单晶X-射线衍射技术对其结构进行了表征。在配合物1中，5-氨基双四唑配体以双齿螯合模式与铜离子配位形成离散的分子，并通过H键作用进一步形成了三维的超分子结构。在配合物2中，强的R22(8)氢键环作用将双核的Pb2(bta)2(en)2单元连接成一维的链，这些链通过与水分子氢键作用被进一步组装成三维的超分子结构。另外，通过DSC技术探究了它们作为添加剂对高氯酸铵的热分解催化影响。研究发现，铅基化合物2的催化效果较铜基化合物1要好。 |
| 关键词: 5-氨基双四唑 配位化合物 高氯酸铵 晶体结构 |
| 基金项目: |
| Abstract: Two coordination compounds with N,N-bis(1H-tetrazole-5-yl)-amine (H2bta), Cu(bta)(bpy)(H2O) (1) and Pb2(bta)2(en)2·4H2O (2) (bpy=2,2′-bipyridyl and en=ethylenediamine), have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. In 1, the H2bta ligands coordinate with Cu2+ ions in the bidentate chelate mode to form discrete molecular structures, which are assembled through extended hydrogen bonds to generate a 3D architecture. 2 presents a 3D supramolecule stucture constructed from 1D chains, in which the binuclear Pb2(bta)2(en)2 units are bridged by the strong hydrogen bond ring motif R22(8). Furthermore, compounds 1 and 2 were explored as additives to promote the thermal decomposition of ammonium perchlorate (AP) by the differential scanning calorimetry techniques (DSC). DSC curves reveal that lead-based compound 2 shows better performance than the copper-based compound 1. CCDC: 855627, 1; 774052, 2. |
| Keywords: N,N-bis(1H-tetrazole-5-yl)-amine coordination compounds ammonium perchlorate crystal structure |
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| 谢 钢,夏正强,陈三平,高胜利.5-氨基双四唑富氮配位化合物的合成、结构及其对高氯酸铵的热分解影响(英文)[J].无机化学学报,2012,28(2):367-373. |
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