| 两个大环二茂铁环蕃的合成与晶体结构(英文) | |||||||||||||
| Synthesis and Crystal Structures of Two Macrocyclic Ferrocenophanes | |||||||||||||
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| 摘要: 本文合成了2个大环硒杂二茂铁环蕃，1，9-二硒杂-5-硫杂[9]二茂铁环蕃(1)和1，9，21，29-四硒杂-5，25-二硫杂[9.9]二茂铁环蕃(2)，并应用核磁、质谱、单晶X-射线衍射进行了表征。循环伏安法测得二茂铁的氧化还原半波电位分别为-30 (81) mV (1)和42(67) mV (2)。 | |||||||||||||
| 关键词: 二茂铁环蕃 晶体结构 电化学 | |||||||||||||
| 基金项目: | |||||||||||||
| Abstract: Two macrocyclic ferrocenophanes, 1,9-diselena-5-sulfur-[9]ferrocenophane (1) and 1,9,21,29-tetraselena -5,25-disulfur-[9.9]ferrocenophane (2), have been prepared. The new compounds have been characterized by 1H NMR spectroscopy, X-ray crystallography and electrochemistry. The CV of 1 and 2 showed one clearly reversible oxidation process with E1/2 value of -30(81) mV and 42(67) mV respectively. CCDC: 849326, 1; 849327, 2. | |||||||||||||
| Keywords: ferrocenophane crystal structure electrochemistry | |||||||||||||
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| 张 鑫,秦言智,肖 飞,景 苏,吉 玮.两个大环二茂铁环蕃的合成与晶体结构(英文)[J].无机化学学报,2012,28(5):1015-1018. | |||||||||||||
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