| 两个由异烟酰胺构筑的钴、镍配合物的合成及晶体结构(英文) | |
| Synthesis and Crystal Structure of Two Complexes of Cobalt, Nickel Assembled by Isonicotinamide | |
| 摘要: 采用溶液培养法，在室温下合成了2个新的过渡金属配合物[Co(inta)2(H2O)4][Co(H2O)6](tdc)2·2H2O (1)和[Ni(inta)2(H2O)4](tdc)·2H2O (2)(inta=异烟酰胺，H2tdc=2,5-噻吩二甲酸)。并对其进行了元素分析、红外光谱、紫外光谱、热重和X-射线单晶衍射测定。这两个配合物通过氢键和π-π相互作用形成了三维超分子网状结构。 | |
| 关键词: 晶体结构 钴配合物 镍配合物 | |
| 基金项目: | |
| Abstract: Two transitional metal complex [Co(inta)2(H2O)4][Co(H2O)6](tdc)2·2H2O (1) and [Ni(inta)2(H2O)4](tdc)·2H2O (2) (inta=isonicotinamide, H2tdc=2,5-thiophenedicarboxylic acid) have been synthesized by employing the solution a preparation method at room temperature. They were structurally characterized by elemental analysis, IR spectrum, UV spectrum, TG and single-crystal X-ray diffraction. They are further extended into a three-dimensional supramolecular network structure through hydrogen bonds and π-π interactions. CCDC: 862125, 1; 862126, 2. | |
| Keywords: crystal structure cobalt complex nickel complex | |
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| 刘 博,李秀梅,周 实,王庆伟,李传碧.两个由异烟酰胺构筑的钴、镍配合物的合成及晶体结构(英文)[J].无机化学学报,2012,28(5):1019-1024. | |
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