| 两个由2-(4′-氯-苯甲酰基)苯甲酸构筑的铜、锌配合物的合成及晶体结构(英文) |
| Synthesis and Crystal Structure of Two Complexes of Copper, Zinc Assembled by 2-(4′-Chlorine-benzoyl)-benzoic Acid |
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| 摘要: 通过水热法合成了2个新的配合物Cu2(cbba)4(phen)2(1)和Zn(cbba)2(bipy)(2)(Hcbba=2-(4′-氯-苯甲酰基)苯甲酸,phen=1,10-邻菲罗啉,bipy=2,2′-联吡啶)，并对其进行了元素分析、红外光谱、热重和X-射线单晶衍射测定。这2个配合物通过π-π相互作用形成了三维超分子网状结构。此外，还研究了配合物2的荧光性质。 |
| 关键词: 水热合成 晶体结构 铜配合物 锌配合物 |
| 基金项目: |
| Abstract: Two complexes Cu2(cbba)4(phen)2 (1) and Zn(cbba)2(bipy) (2) (Hcbba=2-(4′-chlorine-benzoyl)-benzoic acid, phen=1,10-phenanthroline, bipy=2,2′-bipyridine) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. They are further extended into a three-dimensional supramolecular network structure through π-π interactions. Moreover, the luminescent property of complex 2 has been investigated in the solid state. CCDC: 859144, 1; 859145, 2. |
| Keywords: hydrothermal synthesis crystal structure copper complex zinc complex |
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| 李秀梅,牛艳玲,王志涛.两个由2-(4′-氯-苯甲酰基)苯甲酸构筑的铜、锌配合物的合成及晶体结构(英文)[J].无机化学学报,2012,28(8):1769-1774. |
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